Undoped polyaniline/surfactant complex for the corrosion prevention

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National Aeronautics and Space Administration, National Technical Information Service, distributor , [Washington, DC, Springfield, Va
Surfactants., Corrosion prevention., Organic compounds., Protective coat
Other titlesUndoped polyaniline surfactant complex for the corrosion prevention.
StatementLo-Min Liu and Kalle Levon.
Series[NASA contractor report] -- NASA/CR-207459., NASA contractor report -- NASA CR-207459.
ContributionsLevon, Kalle., United States. National Aeronautics and Space Administration.
The Physical Object
Pagination1 v.
ID Numbers
Open LibraryOL15547740M

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Undoped polyaniline–surfactant complex for corrosion prevention. Lo‐Min Liu; Kalle Levon; Pages: ; First Published: 21 July ; Abstract; Full text PDF PDF References; Request permissions; Polymerization of lactides and lactones.

III. Ring‐opening. With the surfactant, DDPh, PANi could be diluted into the coatings and the properties of the coatings were affected. Emeraldine base (EB) form of PANi was also found to be oxidized by the hardener.

The oxidized form of polyaniline provides improved corrosion protection of metals than that of emeraldine base since the value of the standard Author: Kalle Levon and Lo-Min Liu. polyaniline in corrosion protection of metals and alloys is replacement of environmentally hazardous materials, e.g.

chromates in coating systems. Up to day, lot of studies on various metals both on iron, steels and non-ferrous metals and alloys were performed. The studies involve investigation on. 1. Introduction. PANI has been widely studied for a variety of applications in anticorrosion coatings for the past three decades since DeBerry showed in that the electrochemically deposited polyaniline (PANI) protected stainless steel by anodic protection.Until to the present time, two forms of PANI have been the most thoroughly investigated in anticorrosion coatings: these are Cited by: Undoped polyaniline has a conductivity of × 10 −9 S/m, whereas conductivities of × 10 −5 S/m can be achieved by doping to 4% HBr.

The same material can be prepared by oxidation of leucoemeraldine. Synthesis. Although the synthetic methods to produce polyaniline are quite simple, the mechanism of polymerization is probably complex. ported that the dopants in PANI play an important role in corrosion protection due to the formation of an iron-dopant secondary layer.8,10 Hence, a study has been made on the effect of the addition of polyaniline with phosphate and chloride dopants in the epoxy– coal tar system on the corrosion-protection performance of steel in.

Main; Contacts; About the Journal; Subscription; Rules for authors; Editorial board; The Publication Ethics. A method of protecting a metal substrate from corrosion including coating a metal substrate of, e.g., steel, iron or aluminum, with a conductive polymer layer of, e.g., polyaniline, coating upon said metal substrate, and coating the conductive polymer-coated metal substrate with a layer of a topcoat upon the conductive polymer coating layer, is provided, together with the resultant coated.

The most discussed mechanism of PANI coatings in the literature is the so-called ‘ennobling mechanism’, which is Undoped polyaniline/surfactant complex for the corrosion prevention book on the assumption that the ICP acts as oxidizing agent for the leached metal ions (Fig.

b) and hence maintain the metal in the passivity domain by providing a protective thin layer of metal oxide [22,].The concept of the ennobling mechanism by the. CiteSeerX - Document Details (Isaac Councill, Lee Giles, Pradeep Teregowda): Abstract-Conducting polyaniline powder was synthesized chemically and paints containing conducting polyaniline powder were applied on low carbon steel samples.

The conducting polyaniline powder was characterized by UV-Visible absorption spectroscopy and the morphology of paint coating on low carbon steel was studied. This paper describes a model for polyaniline (PANI) corrosion protection and presents data which clearly demonstrate significant corrosion protection in a salt fog environment.

The book includes discussion of reinforcement of polyaniline via addition of carbon-based materials, blends with thermoplastics, thermosets, natural and synthetic rubber, and polyaniline based.

formation of solutions of either the undoped or the doped polymer [1,2]. Other efforts have been directed toward forming dispersions of polyaniline in liquid media [3] or in thermoplastic media [4].

The conductive form of polyaniline is an acid/base complex, which depending on the precursor. About this Item: Independently Published, United States, Paperback. Condition: New. Language: English. Brand new Book.

Due to the strict regulations on the usage of heavy metals as the additives in the coating industries, the search for effective organic corrosion inhibitors in replace of those metal additives has become essential.

Polyaniline (PANI) was doped as lubricating additive to afford grease. The effect of PANI on the physicochemical characteristics, corrosion resistance, and tribological performances of lubricating grease was investigated in details, and the tribological action mechanisms of lubricating grease were analyzed in relation to worn surface analyses by scanning electron microscopy (SEM) and energy.

Part of the Springer Series in Materials Science book series (SSMATERIALS Corrosion prevention with an organic metal (Polyanilin): corrosion test results.

L.M. Liu, and K. Levon. Undoped polyaniline — surfactant complex for corrosion prevention.

Details Undoped polyaniline/surfactant complex for the corrosion prevention FB2

Appl. Polym. Sci.,Vol. A method for increasing the conductivity of polyaniline is disclosed. The method comprises contacting the polyaniline with an ionic surfactant whereupon the conductivity of the polyaniline is increased by a factor of at least about 2.

Also provided are coating compositions which can be prepared by the method. The electrochemical response of polyaniline (PANI) in its undoped intermediate (emeraldine base, EB) oxidation state coated on cold rolled steel (CRS) or glass substrate has been evaluated by X-ray photoelectron spectroscopy (XPS).

The oxidation state of the polymer was determined from the ratio of amine vs imine nitrogen chemical states observed in the N(1s) photoelectron spectrum. Samui, AB, Patankar, AS, Rangarajan, J, Deb, PC, Study of Polyaniline Containing Paint for Corrosion Prevention Prog.

Org. Coat., 47(1) 1–7 () CrossRef Google Scholar Twite, RL, Bierwagen, GP, Review of Alternatives to Chromate for Corrosion Protection of Aluminum Aerospace Alloys Prog. Org. Coat., 33(2) 91– () CrossRef.

Redox-responsive nanocapsules consisting of conductive polyaniline and polypyrrole shells were successfully synthesized by using the interface of miniemulsion droplets as a template for oxidative polymerizations. The redox properties of the capsules were investigated by optical spectroscopies, electron microscopy, and cyclic voltammetry.

Self-healing (SH) chemicals such as diglycidyl ether or. Polyaniline Nanoparticles Prepared by Micro-Emulsion Polymerization for Corrosion Inhibition of Carbon Steel in 1M HCl Rania 1E.

Morsi, E.A.

Description Undoped polyaniline/surfactant complex for the corrosion prevention PDF

Khamis2 1,2Egyptian Petroleum Research Institute, Nasr City, P.B. Cairo,Egypt Abstract: Polyaniline nanoparticles were prepared using oxidation polymerization in micro-emulsionsystem. Sodium. Perovskite is the name given to a crystallographic structure with ABX 3 composition, where 'A' represents a monovalent cation, 'B' a divalent cation and 'X' an anion.

Solar cells based on hybrid organic–inorganic perovskite containing in the A site, organic cations such as methylammonium (CH 3 NH 3 +), formamidinium (HC(NH 2) 2) +; Pb 2+ and Sn 2+ in the B site and a mixture of halides.

Download Undoped polyaniline/surfactant complex for the corrosion prevention FB2

(67), (68) Another mechanism for corrosion protection is suggested to be anodic (i.e., the polyaniline film withdraws change from the metal and passivates its surfaces against corrosion). (76) Based on this mechanism, the role of polyaniline in active corrosion protection is due to its ability to intercept electrons on the metal surface and to.

Polyaniline (PANI) and polyaniline composites with aluminium oxide (Al 2 O 3) were prepared using the in situ polymerization method.

The composites were then blended with acrylic paint and applied to carbon steel panels. The coated steel panels were evaluated for corrosion using the immersion test technique.

() Understanding electrodeposition of polyaniline coatings for corrosion prevention applications using the wire beam electrode method.

Corrosion ScienceOnline publication date: 1. PPy doped with NO -coated SS, PPy-undoped coated SS In corrosion, quantitative information on corrosion currents and PPy-undoped/Al O -coated SS) in the corrosive solution. and corrosion potentials can be extracted from the slope of the 2 3 The corrosion protection effect of polypyrrole films Anti-Corrosion Methods and Materials A.

Ehsani. The polyaniline has electronic, magnetic, and optical properties similar to metals, in addition to the flexibility and processibility of conventional polymers PANI has potential applications in various technologies like electromagnetic shield conductive coati corrosion protect artificial musc bio-sensing Hybrid zinc-based coatings with embedded polyaniline (PANI) particles in the metal matrix are obtained in a one-step process via electrodeposition on low-carbon steel plates.

The aim is directly to use the inhibitor properties of polyaniline for improved protection against corrosion in chloride containing medium (5% NaCl solution). PANI-particles (concentration of g/L) are added to the.

Undoped polyaniline-surfactant complex for corrosion prevention. Liu L-M and Levon K. Appl. Polym. Sci. 73(14),() Effects of various chemicals including endocrine disruptors and analogs on the secretion of Th1 and Th2 cytokines from anti CD3-stimulated mouse spleen cells. Yano K, et al.

Health Sci. 49(3),(). surfactant (emulsifier) and as a dopant [16, 17]. Also surfactant affect on the morphology (degree of crystalline order and orientation) [17].

Particle size and conductivity can be decreased by increasing the concentration of stabilizer [18, 19]. The surfactants influence the physical.Tafel plots showed a lower corrosion rate and a more noble corrosion potential for the polyaniline-coated sample as compared to a bare steel sample.

Electrochemical data confirmed that significant interactions between the polyaniline and steel occurred during the first 5 days of immersion, but that a continuing interaction occurred throughout.surfactants during the polymerization, i.e., micellar and emulsion polymerization systems has largely yielded polyaniline having particulate (non-fibrillar) morphology.

5 There are very few instances where fibrillar morphology has been observed in surfactant-assisted polymerization of .